The can't-miss red carpet looks on your favorite stars from the week's biggest events including Angelina Jolie's effortlessly chic red carpet moment in London to starry New York Fashion Week gatherings.

Over the years, celebrity couples have worn everything from elegant ensembles to daring outfits for their first red-carpet moments together.

See what the biggest stars of film and television wore to make their entrances at the Critics Choice Awards, hosted by Chelsea Handler in Santa Monica, Calif.